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Geological Survey of Estonia, Kreutzwaldi tn 5, Rakvere, 44314, Estonia 20th May 2021 Dear Johannes, Further to recent email correspondence between Geotek and the Geological survey of Estonia, I have great pleasure in providing this technical specification document to you regarding the Geotek MSCL-XYZ-XRF system. We hope that you find the following information useful, and should you require any further information on what is included in this document or on non-destructive core logging then please do not hesitate to contact the undersigned. Yours sincerely, James Shreeve Sales and Marketing Director Geotek Limited. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk GEOTEK MSCL-XYZ-XRF TABLE OF CONTENTS Geotek MSCL-XYZ-XRF ....................................................................................................... 2 1 DOCUMENT OVERVIEW .............................................................................................. 3 2 INTRODUCTION TO GEOTEK........................................................................................ 3 3 MSCL-XYZ-XRF INTRODUCTION ................................................................................... 3 3.1 FACILITY REQUIREMENTS ........................................................................................ 4 3.2 CABINET BASED SySTEM ......................................................................................... 4 3.3 MOTOR CONTROL ................................................................................................... 5 3.4 CORE HANDLING ..................................................................................................... 5 3.5 WHOLE AND/OR SPLIT CORE ................................................................................... 6 3.6 DATA ACQUISITION ................................................................................................. 7 3.7 JUSTIFICATION OF USE – KEY ADVANTAGES OF THE MSCL-XYZ-XRF.......................... 7 4 SPECIFICATIONS ......................................................................................................... 7 4.1 SUMMARY OF SYSTEM FEATURES ........................................................................... 7 4.2 SENSOR OPTIONS AVAILABLE ................................................................................ 10 HIGH-RESOLUTION GEOSCAN VI LINESCAN CAMERA .......................................... 11 ASD LABSPEC CIS, VNIR/SWIR SPECTROMETER ................................................... 14 POINT MAGNETIC SUSCEPTIBILITY ..................................................................... 15 KONIKA MINOLTA COLOUR SPECTROPHOTOMETER ........................................... 16 5 GEOTEK XRF SENSOR TECHNOLOGY - MECHANICS AND SPECIFICATIONS ................... 17 5.1 DEMONSTRATION OF GEOTEK XRF PERFORMANCE ............................................... 19 5.2 XRF RESULTS FROM THE TUFF SAMPLE .................................................................. 19 5.3 LOW ATOMIC NUMBER (Z) SENSITIVITY ................................................................... 3 5.4 REPEATABILITY OF MEASUREMENTS ON A GEOTEK XRF SENSOR ............................. 5 5.5 CALIBRATED GEOTEK XRF DATA VS. LABORATORY XRF DATA................................... 6 GEOTEK XRF SENSOR CONCLUSIONS .................................................................... 6 5.6 GEOTEK SOFTWARE PRODUCTS ............................................................................... 7 GEOTEK ACQUISITION SOFTWARE........................................................................ 7 BAXIL SOFTWARE .............................................................................................. 11 6 GEOTEK SUPPORT AND WARRANTY.......................................................................... 13 6.1 ANNUAL GOLD SERVICE CONTRACT ....................................................................... 14 6.2 ANNUAL SILVER SERVICE CONTRACT ..................................................................... 14 Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk 7 MSCL-XYZ-XRF CUSTOMER REFERENCES ................................................................... 14 1 DOCUMENT OVERVIEW It is understood that the Geological Survey of Estonia ‘EESTI Geoloogiateenistus’ is considering the purchase of a Geotek MSCL-XYZ-XRF core scanning system. The purpose of purchasing such equipment is to acquire invaluable, real-time data from core material investigating geochemical and visual datasets. This document aims to provide technical details regarding the Geotek MSCL-XYZ-XRF. 2 INTRODUCTION TO GEOTEK The study of core samples through Geotek’s Multi Sensor Core Logging platforms (MSCL) has long been recognized (e.g. Schultheiss and Weaver, 1992 or Rothwell, 2006) as a crucial method for deriving a geological stratigraphy, and investigating geophysical and geochemical soil and rock properties. MSCL systems employ a range of non-destructive petrophysical and spectroscopic/geochemical sensors to create a digital high (sub-mm to deci-cm) resolution record of the sub-surface stratigraphy. Founded in 1994, Geotek have grown globally from initially supplying a range of Multi-Sensor Core Logger (MSCL) and X-ray CT systems (XCT), to developing and providing specialist equipment and consultancy services to the research/academic markets, the Oil & Gas industry, the geotechnical markets and the mining & mineral exploration industries. The Geotek MSCL systems enable a suite of geophysical and/or geochemical measurements to be obtained rapidly, accurately and automatically for sediment or rock cores. The rugged nature of the equipment makes it suitable for use in either an onshore laboratory/repository environment or onboard survey and drilling vessels. All of Geotek’s core loggers accept core between 50 mm and 150 mm in diameter and up to 1.55 m in length. Geological cores and materials come in a variety of sizes therefore the MSCL systems are designed for a full range of core material in a variety of liner compositions. To accommodate varying customers’ requirements (both operational and scientific), we provide a range of different core loggers including the MSCL-XYZ-XRF for multi-core scanning. 3 MSCL-XYZ-XRF INTRODUCTION Every core, in any science or engineering field, benefits from non-destructive, geological analysis. Measured values may be used intrinsically for their actual values (eg. elemental data), or as proxies for changes in lithology or depositional environment (eg. magnetic susceptibility or colour variations). The MSCL-XYZ Core Workstation is a popular and well established product within the Geotek customer base, particularly for those interested in scanning core in boxes or who wish to analyse multiple core samples in one core loading process. It is the ideal system for high- resolution lab based studies. System details can be found in Table 1. Geotek offer detailed, high-resolution XRF analysis of rock core or sediment sample surfaces to provide a quantitative assessment of elemental composition of the sample through our Geotek XRF sensor. Due to the automated, high-resolution nature of the MSCL, the XRF datasets can be collected with a repeatable geometry on the core surface and within a time efficient manner with minimum user inputs. An automated process such as this allows users to focus on interpretative tasks rather than data collection. High-resolution XRF logging means Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk that elemental composition can be used to more accurately correlate separate beds between core locations, sediment source areas, or improve the understanding of core composition. An MSCL-XYZ-XRF is the ideal platform to acquire XRF data as it offers a stable and repeatable geometry with each measurement depth co-registered with other spectroscopy or petrophysical sensor measurements. The MSCL-XYZ-XRF sensors move along the core samples (X-axis) moving up and down simultaneously to carefully make contact with the core surface (Z-axis) and acquire measurements. The system is compatible with various spectroscopic parameters and high-resolution visible and UV linescan imaging. The MSCL- XYZ XRF system therefore provides a compact solution for XRF and other non-destructive measurements from split or whole unlined core (Figure 1). Table 1.,System details for MSCL-XYZ-XRF INSTRUMENT DIMENSIONS (L X W X WEIGHT [KG] POWER H) [MM] MSCL-XYZ-XRF 3090 x 1421 x 2180 1200 kg (packed weight 110v to 220 v, single phase. with all accessories Power draw is up to 1.5W Machine weight ~ 800kg) 13A supply 3.1 FACILITY REQUIREMENTS The XYZ will run on single phase, 110v to 220v electrical connections and does not require any additional cooling or additional facilities to be installed. It is recommended that the system is operated using an Uninterruptable Power Supply (UPS) which should be purchased by the customer, if taken offshore or to remote locations. For the high-resolution helium flush XRF sensor, a Helium: 5-10 ml/ min is required. 3.2 CABINET BASED SYSTEM The MSCL-XYZ-XRF is specifically designed to acquire geochemical data from multiple core samples in one scanning period. In its normal configuration, it is cabinet based including a dual-interlock system to prevent accidental exposure of users and passers-by (Figure 1). Furthermore, the cabinet allows the users to move around the system in close proximity and allows the system to be installed into a normal laboratory. The cabinet complies with USA and EU regulations and requirements on closed X-ray cabinet systems. The cabinet surface dose rate is designed to be less than 2.5 µsvh-1. It is fitted with emergency stop buttons on the outside of the cabinet, as well as illumination beacon to warn operators/passers-by of when the X-ray source is energised. Additional warnings are displayed within the software. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Figure 1., Geotek MSCL-XYZ-XRF for scanning split core samples. Sensor options include: XRF, Magnetic susceptibility, colour spectrometry and high-resolution linescan imaging. 3.3 MOTOR CONTROL The MSCL-XYZ benefits from 3 precision ball screws controlled by stepper motors allowing for precision of movement of less than 0.1 mm. As a result, of this precision Geotek have excellent repeatability of measurement position, and can depth co-register each of the sensor measurements with one another. The Z-arm controls the vertical movement and allows the sensors to touch lightly onto the core surface. In order to prevent damage to soft unconsolidated sediments each sensor has a spring tensioner to remove the weight of the sensor from the surface of the core and hence prevent damage. 3.4 CORE HANDLING The MSCL-XYZ benefits from a horizontal core loading. Each core section is placed onto a retractable core bed by the user (Figure 2). The cores may be placed onto a set of rails which hold single core sections of up to 1.55m in length or into a bespoke core boxes/holders prior to scanning (Figure 1). The user pushes the core bed into the cabinet and closes the front shielding door. At this point, the scanning may be set-up using the MSCL-XYZ software and scanning may commence (Figure 3). The MSCL-XYZ can hold a maximum of either: • Seven (7) x 1.55 m long sediment or rock cores • Two (2) x 3ft core boxes Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Figure 2., MSCL-XYZ-XRF user placing core samples onto the core bed prior to scanning. Figure 3., Geotek MSCL-XYZ-XRF sensors translating over multiple core samples to acquire geochemical datasets simultaneously 3.5 WHOLE AND/OR SPLIT CORE The MSCL-XYZ-XRF accepts nearly any form of core material. Depending on the mechanical configuration of the sensors, data may be obtained from either whole core sections or from split core sections contained in plastic liners. Generally, individual core sections between 50-150 mm in diameter and up to 1.55m in length can be logged at spatial intervals as low as a few millimetres. The data acquisition Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk configuration (which sensors are active and at what spatial intervals they collect data) can be fully defined by the user and changed between core sections as desired. Should the project require the cores to be split, Geotek has developed a core splitter to uniformly cut sediment cores acquired in plastic liners longitudinally creating a flat and reproducible core surface upon which future measurements can be acquired. Immediately following core-splitting, Geotek can provide high-resolution core photography in visible or ultraviolet fluorescence using the GeoScan VI Linescan Imaging camera integrated on the MSCL-XYZ-XRF. The resulting linescans provide an invaluable record of the fresh core surface before any sub-sampling or oxidation can take effect. 3.6 DATA ACQUISITION Acquisition of MSCL parameters from the core surface is conducted through Geotek developed, Geoscientist-friendly software. The software uniquely allows the user to choose measurement resolution (sub-mm to deci-cm scale), or select specific measurement points for each core section. In addition, calibration of the sensors and integration times for each measurement is controlled through the Geotek software. During acquisition, the high-resolution core imaging will typically be conducted first using UV or visible light. Once completed, the MSCL point sensors will acquire data simultaneously at the desired logging resolution. The data for each sensor are displayed live during logging and the user can conduct basic visualisation of the MSCL data. The acquisition speed of the instrument can vary depending on the sensor arrangements selected, count times for each sensor and the desired logging resolution, the finer the resolution the longer the scan time. However, typically logging speeds can range between 10 and 60 minutes per metre. 3.7 JUSTIFICATION OF USE – KEY ADVANTAGES OF THE MSCL-XYZ-XRF The MSCL-XYZ model has the ability to load multiple cores or specific core boxes at once and as a result is particularly valuable in a repository environment or where large core throughput is required without user intervention. It is common for core repositories or laboratories to utilise handheld instruments such as XRFs, VNIR/SWIR spectrometer’s and DSLR cameras. However, typically these measurements are acquired by hand with one operator in charge of each measurement. As a result, handheld measurements are usually at low resolution intervals downcore and are time consuming to acquire. The MSCL-XYZ XRF can integrate multiple sensors onto a single platform and the automatically acquire these multiple datasets at co-registered depths downcore. A Core Workstation can therefore free up staff from laborious manual measurements allowing them to focus on data analysis, and increase productivity through a core repository, institution, or industrial laboratory. 4 SPECIFICATIONS 4.1 SUMMARY OF SYSTEM FEATURES The MSCL-XYZ-XRF is predominantly designed around the acquisition of XRF datasets using the ultra-sensitive Geotek XRF sensor head. This sensor is installed within a shielded cabinet with dual-interlocked doors. Further detailed information on the Geotek XRF sensor is provided in Table 2). Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Table 2., MSCL-XYZ-XRF specifications with particular reference to the Geotek XRF sensor. EQUIPMENT SPECIFICATION System type Multi-core workstation with retractable core bed and rails sets/bespoke core boxes with cabinet lining Core types Ideally split cores up to 1.55 m in length and up to 150mm in diameter. Possible to take measurements from whole core also, but point sensor technology works better with a flat surface. Accepts whole, 2/3 cut, square cut, and 1.2 cut cores Core Loading Horizontal core mounting and scanning position Sensor motion Fully automated motion in the horizontal and vertical axes. Linear precision: 0.01 mm. All point sensors are moved in unison and collect data in parallel. Contact sensors have adjustable counterbalancing to prevent damage to core surface. Automated and software controlled sensor acquisition with contact sensor measurements acquired simultaneously for efficient data acquisition. Tab-delimited ASCII files containing all measured parameters Data Output vs. depth in section and core: elemental concentrations, spectral reflectance data by wavelength band, magnetic susceptibility. 25, 50, or 100 µm per pixel with outputs of 16-bit RGB TIFF Linescan image outputs images. Data acquisition rates highly dependent on the user setup and Core Processing Speed sampling interval. A typical scan for only XRF would include a calibrated set-up for 22 elements (acquired from calibration). Example: Using a 5 second count time per beam, at a 1 cm logging interval, allows the user to scan 1 m every 40 minutes. Geotek XRF X-ray Up to 50 kV and 15 W, Rh anode allowing sulfur detection, air- source cooled, 50 μm Be window. (>25,000 active hours, or 50,000 installation hours) 2 Geotek XRF X-ray RaySpec SiriusSD Silicon Drift Detector, 30 mm x 0.45 μm, detector FWHM: down to 129 eV at Mn Kα, (8 μm) Be window. Geotek XRF Spectral The Geotek XRF head can operate in two distinct ways – analysis calibrated and uncalibrated: The calibrated mode uses a tuned fundamental parameters technique to convert elemental peaks in the collected spectra to semi-quantitative concentrations in parts-per-million (ppm) for the possible 22 elements. The uncalibrated mode simply collects the raw XRF spectra for given beam conditions that the user can specify depending on which elements they are interested in – certain beam conditions are optimised (excitation and filtering) for certain ranges of elements. Using bAxil software the spectra can be analysed to determine the intensity (counts or counts/s) of Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk individual element peaks (many more than the possible 22 elements in the calibrated mode). This is a technique commonly used in academia for looking at changes in the rock and sediment chemistry, specifically using elemental ratios (eg Fe/Ti, Sr/Ca). Elements detected in the Na to U Geotek XRF Geotek XRF Downcore 10, 1 or, 0.1 mm using motorised slits resolution Geotek XRF Cross-core 5, 10, or 15 mm using manual collimators resolution Core accepted Diameter: 55-150 mm; Length: up to 155 cm Radiation shielding and 3 mm of steel on all sides with dual interlocks on doors safety Electronics and PC Integrated electronics and computer system. Supplied with a Windows 10 PC. Electronics rack 55 cm x 60 cm x 60 cm (L x W x H) Compatible Sensor Geotek high-sensitivity XRF technology High-resolution Geoscan VI linescan camera (with option of UV imaging also) Point magnetic susceptibility VNIR/SWIR spectrometry using ASD Labspec Colour spectrophotometry (Using either ASD VNIR/SWIR or Konica Minolta) Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk 4.2 SENSOR OPTIONS AVAILABLE The Geotek MSCL-XYZ-XRF system offers a unique opportunity to invest in a state-of-the-art core characterisation platform that deliver geochemical data from various sensor technologies. Geological core material is precious and often irreplaceable and in order to maximise data recovery from every cm a laboratory must turn to non-destructive sensor technology such as those described in Table 3). Table 3., Summary of Available Geotek Sensor Technology GEOTEK SENSOR PERFORMANCE DATA OUTPUT ADVANTAGE TECHNOLOGY STATISTICS • 100, 200, 400, and • 16-bit TIFF • Low, medium and high 500 ppcm over 4” core • XML Metadata resolution settings filesRGB Colour Geoscan VI Visible width without camera change Profile as ASCII and UV Light • Speed 30s per m for • No geometrical visible light at 200 distortionQuantitative ppcm colour analysis for consistent core description • Area of measurement: • Measurements • Determination of clay, presented against c.10 mm2 / alteration, Fe-ore, and depth in ASCII file / • Speed: 10s per carbonate mineralogy / measurement / • Data interpretation ASD LabSpec performed by Geotek VNIR/SWIR • Spectral Resolution /: with purchase of Spectrometer 3 nm @700 nm; 10 MinSpec software nm @ 1400 nm/ 2100 nm • Range /: 400 nm to 2600 nm • Area of measurement: • Measurements • Fantastic borehole presented against c.10 mm2 / / correlation depth in ASCII file • Speed: 2s – 30s per • Sediment provenance Point Magnetic tool due to stratigraphic Susceptibility measurement / constraints on meter • Sensor sensitivity: 1 x deposition of magnetic SI x10-6 / / minerals / • Range: 26 SI • Area of illumination: • Measurements • Quantitative colour c.3 or 8 mm presented against analysis with Munsell • Speed: 2s per depth in ASCII file colour code for Colour measurement • Colour exported in consistent core Spectrophotometer • Spectral range: following colour description 400 nm to 700 nm spaces: CIE, RGB, • Fantastic well to well • Spectral resolution: XYZ and Munsell correlation tool 10 nm • Elements reported • Spectra exported • Ultimate light energy between Na and U as as ASCII files performance from peak area [cps] • Element ppm dedicated ED-XRF • Up to 24 elements concentrations and spectrometer presented as ppm error reported • Determine Mg, Ca, Fe, Geotek XRF Spectrometer • Speed: 2s – 30s per against depth in Mn concentrations for measurement ASCII file carbonate speciation • Fully computer • Peak area cps • Determination of controlled for highest reported from sediment provenance precision and spectral analysis from elemental repeatability software as ASCII distribution such as Ti- flux Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk GEOTEK SENSOR PERFORMANCE DATA OUTPUT ADVANTAGE TECHNOLOGY STATISTICS • Helium-flushed • Development of measurement cell for chemostratigraphic ultra-sensitivity of light models for tectosilicate energy elements such mineralogy as: Na, Mg, Ai, Si • Improve well to well • Full user control over correlation and regional beam conditions, geological model filters, and model through geochemistry fitting HIGH-RESOLUTION GEOSCAN VI LINESCAN CAMERA Figure 4., Geoscan VI high-resolution linescan camera with VIS and UV lightbox The Geoscan VI linescan camera operates by acquiring single lines of image data sequentially down the core. Linescan images are far superior to area camera images because they do not suffer from uneven lighting, spherical distortion, montage or “stitching” effects (Figure 4). The camera captures images with a high dynamic range, allowing comparisons between light and dark cores. In addition, they will achieve higher resolution (greater number of pixels per cm (ppcm) for long thin objects like core samples. The Geoscan VI camera has one massive c.5340 pixel CCD and is equipped with automatic focus and aperture routines integrated into Geotek’s custom-designed user friendly software for straightforward, simple and quick set-up. Furthermore, specular reflectance caused from water/fluid-saturated cores is removed through cross-polarisation of the light source and the lens; improving clarity and image detail (Figure 6). Incoming light is passed through a set of red, green, and blue filters to produce true independent colour separation. Averaged image data can be converted to these RGB values and saved in a separate file to facilitate quantitative comparisons of colour between cores and other downcore measurements (Figure 7). The camera is factory-calibrated and a standard photographic 90% white, or 18% grey card is used for field calibration. Lighting and aperture settings are software controlled ensuring that images can be qualitatively or quantitatively compared to each other. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Even though the Geoscan VI is one camera it is capable of imaging cores at multiple resolutions. This means that the core imaging system can be used for standard scanning for data archival but also for high resolution scanning for potential image analysis routines or for detailed microscope-level imaging over specific areas of the core. The following image resolutions are available over the full width of a 4” core: 100, 200, 400, and 500 pixels per cm. Images are output as 16-bit RGB TIFF images but are quickly and easily converted to JPEG or other formats as required. RGB Colour Profile as ASCII. Each Geotek core section image has a companion XML metadata file, containing important metadata pertaining to the core section and imaging conditions. A ruler can be generated next to the image, depicting either depth in core section or depth in core. Figure 5., Example image of 4" core sample from Geoscan V at 200 pixels per cm in visible light Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Figure 6., Example core image at 500 pixels per cm. The left is of dry core surface; the right is of a fully saturated wet core surface; note there is no bright spots of oversaturation from specular reflectance as all specular reflectance from the fluid on the surface was removed using the Geotek cross-polarisation technique Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Figure 7., Example of RGB profile extract from Geoscan V core image (e.g. Nederbragt et al., 2006) Ultraviolet images are acquired in the same manner as visible. If the user wishes to automatically collect a UV image after a visible image, both the visible and UV boxes should be checked on the “Add Core Section” pane, in the MSCL software. After the visible image is collected, the system will prepare to collect an ultraviolet image. On the XYZ, the camera will move back to the top of the section, and the software will prompt the user if the aperture requires changing. The software will also prompt the user to change the aperture if necessary. ASD LABSPEC CIS, VNIR/SWIR SPECTROMETER Geotek has integrated ASD’s LabSpec 4 analyser onto the MSCL-XYZ_XRF platform. The sample is illuminated by the integral halogen light source through a fibre optic link. The spectrometer returns data from c.350-2500 nm which is collected and displayed in the MSCL software alongside other geochemistry datasets acquired. The ASD Labspec 4 visible, very near infrared (VNIR), and short wavelength infrared (SWIR) spectrometer measures the vibrational bonds of molecules and their overtones, seen as absorptions in reflected light (e.g. Hunt, 2014). The sensor is able to determine mineralogy and colour information from the surface of the core. However, unlike the hyperspectral camera this sensor using a point probe with a measurement area of approximately 10 mm2. The sensor probe touches lightly onto the core surface and acquires the measurement at a discrete point. As a result, the Labspec 4 sensor does not produce maps. Spectra per measurement point is saved and displayed in the MSCL software in real-time. Mineralogical interpretation are provided Geotek Minspec software and outputted against depth. The format is ready for databasing and is compatible with a wide range of database inputs. The spectra are stored in the cloud by project paths, with a user permission system for Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk users to access the data for their projects and for manager/supervisor level users to have access to all company projects globally. The mineral composition logs extracted from the core and displayed in the MSCL software enable geoscientists to more confidently determine the interrelationship between mineralogy and lithology through physical and chemical characteristics, thereby improving the lithological description and stratigraphic correlation of geological formations. Figure 8: Example output of ASD Labspec 4 infrared spectrometry data on left and XRF data on the right. Displayed in Geotek MSCL Acquisition Software POINT MAGNETIC SUSCEPTIBILITY Alterations in the magnetic susceptibility within core samples are often stratigraphic. Therefore, magnetic susceptibility records are an excellent well to well correlation tool. In addition, the tool can be used to determine the lithological properties as well as any changes in sediment provenance and/or diagenetic environment. An example of a magnetic susceptibility dataset is presented in Figure 9. At about 10 ft into the example section an 8 ft thick bed of raised magnetic susceptibility measurements are recorded indicating that the composition of the core is more magnetic, this is normal for clay-rich or Fe-rich beds. This interpretation is confirmed by the XRF data which shows elevated Al and Fe within this interval. Although obvious from the data profiles it is not obvious from the visible images, highlighting the value of continuous multi-sensor parameter profiles in understand core heterogeneity. Magnetic susceptibility has also been shown to be useful in determining illite content (Potter et al., 2004) or looking into the anisotropy of shale sequences (Ebufegha and Potter, 2014). Geotek provide the Bartington MS2E point sensor with the MSCL-XYZ-XRF system as an additional sensor option. This is electronically calibrated to measure a single standard of stable iron oxide tested and analysed by Bartington. The data acquired using the MS2E sensor can be presented as uncorrected mass specific magnetic susceptibility. The Bartington point sensor (MS2E) is used for surface scanning and providing high-resolution surface measurements on split sediment or slabbed rock cores. Magnetic susceptibility data is collected through use of the MS2E probe and MS3 meter. The data is displayed in the custom Geotek MSCL software and may be exported as ascii files for further analysis and to created downcore profiles. Alterations in the magnetic susceptibility within core samples are often stratigraphic. Therefore magnetic susceptibility records are an excellent core to core correlation tool. In addition, the tool can be used to determine the lithological properties as well as any changes in sediment provenance and/or diagenetic environment. Magnetic susceptibility measurements can be Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk used as proxy for permeability measurements, and in the mining industry the susceptibility of the core material can be used to determine the occurrence of volcanics and to feed into magnetic anomaly models for geophysical surveys. Figure 9., Figure 8: Example of core imagery, magnetic susceptibility, colour and XRF data presented against depth, core colour (L*,a* and b*), and magnetic susceptibility. The core is from a conventional North Sea Reservoir and is a section of the Brent Formation. Note the peaks in Zr, which are interpreted as influxes of terrestrial sourced material into the basin KONIKA MINOLTA COLOUR SPECTROPHOTOMETER Defining the colour of a rock samples is probably the most subjective measurement of any visual description because the perception of colour is dependent not only on how each of our brains individually interprets incoming light but also on light levels, colour of the light, and even the weather outside. As a result, one of the most fundamental descriptive tools of geology - colour can often be one of the least reliable. Colour spectrophotometry is a spectroscopic technique that measures reflectance between 360 nm and 740 nm at 10 nm intervals to accurately define colour to remove subjectivity and improve consistency across visual descriptions. Ultimately a colour spectrophotometer allows colour to become a powerful lithology indicator and correlation tool (e.g. Rogerson et al., 2006) Figure 9). Colour profiles can be exported directly from the Geoscan V images (e.g. Nederbragt et al., 2006), however, if the user requires colour with different colour spaces or a quantified Munsell colour code then Geotek recommend the Konica Minolta CM700d colour spectrophotometer. A colour spectrophotometer is used to accurately define the spectral colour of the core. The sensor head contacts the surface of the core which is normally covered a thin transparent plastic film (‘clingfilm’, or similar products). This measurement enables accurate colour analysis to be made at spatial intervals as low as 3mm (using a 3mm aperture compared with the normal 8mm aperture). The data is used to report Munsell colours (if required) as well as generating a simulated colour core for diagrammatic purposes where a detailed image is not required or available. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk It is important to note that the ASD Labspec also presents colour data, therefore the Konica Minolta is optional here. 5 GEOTEK XRF SENSOR TECHNOLOGY - MECHANICS AND SPECIFICATIONS The ultra-sensitive Geotek XRF spectrometer is designed for class leading light energy element (e.g Na, Mg, Al, Si) sensitivity to provide elemental distribution and abundances from the surface of geological samples. It can be installed on a variety of Geotek MSCL systems including the MSCL-XYZ. Innovative close-coupled geometry with a market leading X-ray detector and signal processing technology delivers impressive count rates at high spectral resolutions without the sacrifice of measurement speed. Geotek XRF software features easy to use set-up windows giving the user flexibility of measurement conditions and areas of illuminations; so whether focused on palaeoclimate research, or oil and gas chemostratigraphy, the Geotek XRF should fit into your workflow. The Geotek XRF Sensor uses a 15W, 50kV sealed source, and as a result of its sealed and low power nature, it is highly reliable (25,000 hours). This source life value is the number of hours that the source can be utilised for, this number does not reflect time in which the source is not being used. The Geotek high-resolution, helium-flush XRF utilises a closed source. The benefit of utilising this type of source mean that the system does not require any additional cooling to maintain temperatures. This would mean less maintenance would be needed in comparison to an open source system. The design of the Geotek XRF sensor is focussed around shortening the source-object- detector distance, and creating the right incident angle to collect as many fluorescence counts as possible to offer the best sensitivity for low energy fluorescence X-rays (Na, Mg, Al, Si). To further improve the sensitivity of light energy elements the Geotek XRF sensor utilises a closed helium-flushed measurement cell, which is placed directly onto the sample surface. The Helium reduces the absorption of the low energy fluorescence X-rays (in particular Na, Mg, Al and Si) significantly improving sensitivity for these lighter elements. The limits of detections as such, can be found in the Limits of Detection (LOD’s) document. The Geotek XRF sensor uses the latest SDD detector technology with cube-preamplification for improved count rate. The detector has a collimated area of 30 mm2, which is one of the largest detectors for high resolution scanning on the market. The Geotek XRF sensor, therefore, boasts an impressive performance at low peaking times, resulting in high output count rates (c.200,000 ocr) with excellent resolution c.133eV. The >15,000 peak to background ratio combined with the high resolution and short source-object-detector distance design results in excellent sensitivity for light elements. In addition, this detector technology enables the analysis of the Sodium (Na). The XRF sensor uses a series of filters of different z-values and thickness, whilst operating the source at different kV settings to gain the full spectrum of elements. The system therefore has a ‘standard' two beam mode, whereby the same measurement point is measured twice. The standard beam modes use 10kV with no filter for the lower energy elements, and 40kV with 125 micron of silver filter for the higher energy elements. Geotek proprietary software and a set of calibration pieces are then fed into a fundamental parameters algorithm to produce quantification of elements from the core surface. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk The collimator enables the cross-core irradiated sample area. It can be set to 15, 10, and 5 mm and must be manually changed. Filters can be changed by moving the motorised filter/shutter assembly. Helium flushing: Air along the X-ray path will absorb a part of the X-ray fluorescence, particularly that of light elements. Moreover, air above the sample will provide an argon peak in the spectrum. With He-flushing the air above the sample will be removed thus the Ar peak will disappear from the spectra. Moreover, peak intensities of light elements, such as Mg, Al, and Si, will considerably increase because He gas absorbs very little of the x-ray fluorescence. The two windows of the measuring cell are covered with 4μm thick film. These films can be easily replaced if they become punctured by the core surface. The irradiated downcore sample area can be varied with the motorised variable slit between 10 and 0.1mm. The Geotek XRF sensor delivers superb light energy element performance at resolutions down to 0.1 mm making the sensor perfect for detailed studies on highly laminated sediments. The latest advances in X-ray detector technology and digital signal processing coupled with an improved helium flushed cell and new filter wheel mechanism produce higher spectral resolution without the sacrifice of measurement time. • The ultra-sensitive Geotek X-ray fluorescence (XRF) spectrometer acquires precise elemental abundances from the surface of sediment and rock cores, and offers superior sensitivity for light elements. • High performance large area silicon drift detector (SDD) with a helium-flushed measurement cell dramatically improves sensitivity, especially for the light elements such as Na, Mg, Al, and Si • Widest range of elements from Na to U at ppm levels • Motorised X-ray slits enable a downcore spatial resolution of 100 μm or less • Sophisticated filter slide to lower detection limits across a wide range of elements, and allows different cross-core areas to be illuminated – perfect for high-resolution studies of dipping laminae • Low-power sealed X-ray source for long life (>25,000 hours) with no maintenance • A unique close-coupled geometry for high efficiency at low X-ray tube power • Simple to use custom-designed software automatically communicates with the logger to acquire, interpret, and display the fluorescence spectra with element abundance during acquisition • Precise measurements are assured through a combination of peak fit and deconvolution algorithms using a proprietary quantitative analysis suite The Geotek XRF head can operate in two distinct approaches – calibrated and uncalibrated, the differences as follows: • The calibrated mode uses a tuned fundamental parameters technique to convert elemental peaks in the collected spectra to semi-quantitative concentrations in parts- per-million (ppm) for the possible 22 elements. • The uncalibrated mode simply collects the raw XRF spectra for given beam conditions that the user can specify depending on which elements they are interested in – certain beam conditions are optimised (excitation and filtering) for certain ranges of elements. Using bAxil software the spectra can be analysed to determine the intensity (counts or Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk counts/s) of individual element peaks (many more than the possible 22 elements in the calibrated mode). This is a technique commonly used in academia for looking at changes in the rock and sediment chemistry, specifically using elemental ratios (eg Fe/Ti, Sr/Ca). 5.1 DEMONSTRATION OF GEOTEK XRF PERFORMANCE A Pre-Cambrian Tuff hand specimen sample was provided to Geotek for XRF analysis, photography and X-ray imaging. Whilst a range of properties can be acquired from this geological sample this document will focus on the XRF data as requested. The data were acquired on a Geotek MSCL-XYZ XRF. However, it should be noted that the same dataset can be acquired on the Geotek MSCL-XYZ XRF offering the same excellent performance, analytic resolution, and repeatability of measurements. The sample was kindly donated by the National Geological Repository, British Geological Survey. 5.2 XRF RESULTS FROM THE TUFF SAMPLE A visible image of the sample was collected at 25 µm per pixel resolution with the sample surface wetted and with a cross-polarisation technique applied to the light source and lens used to reduce specular reflection. This results in a spectacular image as illustrated in Figure 10. Although, note the resolution of the image has been reduced for the purposes of this report. The profiles of XRF data were acquired using the Geotek XRF system at downcore resolutions of 10 mm (blue curve in Figure 10) and 0.1 mm (red curve in Figure 10) along the full length of the sample both with a step size of 0.1 mm. An example of this data (Ca profile in ppm) is presented alongside the image, its position indicated by a white line (Figure 10, left image). The 0.1 mm profile clearly demonstrates the resolution capabilities of the Geotek XRF and picks out features and laminations that are clear from the image. A comparison between the 0.1 mm and 10 mm profiles shows excellent correlation with respect to measured ppm values highlighting the excellent repeatability of the Geotek XRF sensor and MSCL systems. The 0.1 mm step size profiles took 14.5 hours to acquire and 10 mm step size profile (although not presented) took 9 minutes to acquire. A 2D XRF mapping program was also run over a small area of the sample (2.1 cm cross core and 6 cm down core) at a bin size of 0.1 mm x 1 mm (downcore x cross core). An example map (Ca, %) is also presented alongside the image, its position indicated by the white rectangle. As with the profile the high-resolution mode demonstrates its value in picking out fine scale features both down core and cross core. All downcore profile XRF measurements were made under a helium atmosphere using a cross core aperture of 15 mm. This represents an illumination area of 15 x 10 mm and 15 x 0.1 mm for the measurements described above. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk 10mm and 0.1 mm 20 µm Downcore Resolution 6 x 2 cm Image Profiles (Ca ppm) Map (Ca % ) Note: The white box indicates the ar ea of the surface map. The white line indicates the position of the downcor e profiles. Figure 10., Summary of Results for Tuff sample Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk 5.3 LOW ATOMIC NUMBER (Z) SENSITIVITY The Geotek system is capable of detecting Na in percentage levels. Two examples of spectra demonstrating this are shown below. The upper of the two shows a definite peak area for Na at a level of approximately 1% (Figure 11), the lower of the two spectra represents a Na concentration at approximately 0.5 % (Figure 12). Note also in the upper spectrum the Mg peak, representing a concentration of approximately 0.0014 %. These two spectra also show excellent signal to noise characteristics (Note: measurements made using a live time of 30 seconds and an illumination area of 15 x 10 mm) Figure 11., Example XRF spectra showing detection of low atomic number (z) elements. The green area is the brehmsstrahlung, light red is the escape peaks and the dark red are the sum peaks. Yellow is the peak area and what is used for calculation of peak areas counts per second and concentration. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Figure 12., Example XRF spectra showing detection of low atomic number (z) elements. The green area is the brehmsstrahlung, light red is the escape peaks and the dark red are the sum peaks. Yellow is the peak area and what is used for calculation of peak areas counts per second and concentration. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk 5.4 REPEATABILITY OF MEASUREMENTS ON A GEOTEK XRF SENSOR Repeat runs at different measurement times were run to show the repeatability of the system and the noise levels to be expected at different timings; 6 seconds, 3 seconds and 1 second live times. The plot below (Figure 13) demonstrates the system repeatability run to run and the noise level increase with reduced measurement times. All measurements made with an illumination area of 15 x 10 mm. 30000 25000 20000 Ca (ppm) 15000 6 secs 3 secs 1 secs 10000 5000 0 0 20 40 60 80 100 120 140 160 180 Depth (mm) Figure 13., Repeat XRF profile at the same core positions with different measurement times to show repeatability of measurements. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk 5.5 CALIBRATED GEOTEK XRF DATA VS. LABORATORY XRF DATA Data collected from a prepared shale sample (fused beads and pressed pellets) from an accredited laboratory have been compared with data from the Geotek XRF measured directly on the split core surface, these data are shown below (Table 4) and demonstrate an excellent correlation especially when considered the reported porosity of the shale (between 1 and 5%). The measurement of the shale using the Geotek XRF was made using an illumination area of 15 x 10 mm and a live time of 30 seconds. Whilst it would be possible to run the same experiment using a standard rock piece Geotek have opted for using a typical shale sample which is more typical of the types of clay-rich material. This test gives a better representation of how accurate the Geotek XRF sensor will be for normal logging practises. Table 4., Comparison of conventional XRF measurements on a fused bead and pellet sample and Geotek XRF sensor on a bare rock surface ELEMENT LAB ANALYSIS* GEOTEK XRF ANALYSIS** ANALYSED Data Presented at % Mg 1.21 1.01 Al 9.99 9.79 Si 28.86 28.28 P 0.06 0.03 S 0.10 0.00 K 2.86 2.80 Ca 0.33 0.20 Ti 0.59 0.29 Mn 0.08 0.11 Fe 5.00 4.90 Ba 0.05 0.08 Data Presented as ppm V 7.5 37 Cr 1 60 Ni 3.5 9 Cu 3 3 Zn 10.5 14 As 1 0 Sr 52 0 Zr 1 0 Notes: * Measurements acquired from specially prepared fused beads and pressed pellets ** Measurements acquired from slabbed core surface with no preparation, a 15 mm x 10 mm area of illumination with a 30 second count time (dwell time) Analysis was performed on a Delabole Slate sample with a porosity of 1-5% GEOTEK XRF SENSOR CONCLUSIONS The high resolution XRF profiling (0.1 mm downcore resolution) of the tuff sample from Section 5.2 demonstrates the capability of the Geotek XRF to pick out very fine scale features without the blooming effect typically seen in system where the sample is not shielded. The Geotek XRF systems design of the close coupled geometry of the source and detector to the sample acts to significantly increase the signal to noise ratio of the data whilst keeping the Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk source power low. The overlay of the lower resolution profile (10 mm) indicates the repeatability of the measurements using different geometries and highlights that multi- resolution studies can be carried out on core samples with confidence. The 2D map of the part of the tuff surface (Figure 10) demonstrates the capability of the Geotek XRF to collect extremely high resolution data, accurately located in relation to other data, over a relatively large area and shows how well the mapping feature can pick out fine scale features in both cross and downcore axes. The low Z (atomic number) sensitivity of the Geotek XRF is demonstrated in the example spectra presented and the positive identification of Sodium (Na) in a core scanning XRF is unprecedented. The repeatability of the system and the signal to noise levels are shown to change is differing times of measurement – repeatability is excellent and as expected noise levels increase with decreasing measurement times. The calibrated data from the Geotek XRF data show excellent agreement with laboratory XRF data despite the known difficulties of inter-calibration between laboratory and core scanning XRF systems – these include, grain size, surface roughness, matrix and porosity effects. 5.6 GEOTEK SOFTWARE PRODUCTS Geotek deliver our MSCL-XYZ-XRF with custom geoscience-focussed software packages that allow the user to export data along with its metadata. This metadata includes: core name, section number, core depth, sample length, and acquisition parameters, including beam conditions, live/dead time, and measurement times. The system is equipped with a custom Geotek acquisition software package and specialised XRF processing software for determining elemental concentrations. This XRF processing software employs a proprietary fundamental parameter approach and provides concentration data for 22 key elements. These 22 key elements are used as a Geotek standard for calibration purposes, but further elemental identification is possible at a client by client basis. Additionally, Geotek provide bAxil spectral analysis software, which determines the peak area (counts) for individual elements that can then be used for elemental ratioing. The Geotek acquisition software package displays raw and processed datasets from XRF and other contact sensors immediately following sensor measurement. This allows for real-time analysis and decision making to occur for various geological projects in the field or lab space. GEOTEK ACQUISITION SOFTWARE Starting any new core logging project requires the user operator to open the MSCL-XYZ Acquisition software so they may log a new core. This displays the New Section panel, in which a user can input the correct core identification (name, section number, depth, length) and select the acquisition settings desired such as the sampling interval and the measurement times for certain sensors such as XRF (Figure 14). Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Figure 14., MSCL-XYZ-XRF Set-up window display Prior to logging the Geotek XRF sensor must be setup using the XRF Controller window in the MSCL-XYZ Acquisition software. While automated logging is taking place the sensor parameters and the spectra being collected can be viewed in the XRF Controller window but not changed or interrogated. Data is plotted in the MSCL Spectral Data Display along with data from the magnetic susceptibility sensor and colour spectrophotometer, if installed. However, the XRF Controller can also be controlled separately using a piece of additional software called Geotek Utilities. This is designed for testing purposes to determine the optimum mode and measurement times for the particular material being measured, or for collecting spectra from discrete samples. (Figure 15). Data for each measurement point is continuously displayed in the XRF Controller Pane as it is acquired, including the raw XRF spectrum. This window can also be viewed during automated logging from the XRF menu in the ‘MSCL Data Display.’ During the logging of cores, the software automatically controls the XRF sensor. The interface to the device through this Main tab allows the user to: • Select the mode to use (measurement atmosphere + cross-core aperture x slit width) • Define the time of measurement per beam • Switch on and off the x-ray source Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk • Start and stop measurements • See the spectrum being acquired and the conditions used to collect it (x-ray tube voltage and current) • See the current time of measurement (live, real and dead time) Figure 15., Geotek XRF controller interface window From this XRF Control window the user can modify or create individual modes to suit their needs using the Mode Browser. Adjustable features of the XRF modes include the beam conditions (kV, µA), the area of illumination, the number of beams within a mode and the beam filter material (Al, Ag, Cu). The advanced tab in the XRF Controller shows more details of the system including the X-ray tube voltage (kV), current (µA), and temperature, the temperature of the high voltage power supply, the downcore slit width and cross core aperture width, and the filter in front of the source (Figure 16). Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Figure 16., Geotek Modes Browser where individual modes can be edited or created. Figure 17., Advanced Panel where the XRF head hardware status can be viewed. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk During logging core, data is displayed as elemental abundances in ppm (parts per million). The elemental abundances come directly from the Geotek XRF sensor head, which feeds into the acquisition software, which displays the spectra and elemental data (Figure 9). For each XRF measurement point, the spectrum is displayed. The spectral window supports zooming for detailed inspection and further analysis whilst logging. Elements can be plotted on a single graph, or can be plotted in individual graphs (Figure 18) Figure 18., MSCL Spectral Data Display showing, from the left, XRF spectra, XRF element data in %, laser profile of the core height, magnetic susceptibility, and total XRF counts. BAXIL SOFTWARE Geotek provide the bAxil spectral analysis software to analyse the elemental data. The bAxil software processes the spectra using a basic template that defines each element and from that may calculate the peak area for the user. The bAxil application software, offered with the MSCL-XYZ-XRF, is a software developed for the analysis of energy-distributed X-ray spectra. The software also performs quantitative analysis using different methods. bAxil spectrum analysis algorithms are based on the well- known AXIL spectrum analysis methods. This new implementation summarizes the working experience and feedback over more than 30 years from a large AXIL user’s community. bAxil algorithms and graphical user interface sum up the coding experiences over all these years while, at the same time, incorporates new and powerful programming techniques. The bAxil’s spectrum analysis engine is based on the internationally well-known AXIL (Analysis of X-ray spectra by Iterative Least Squares) fitting routines. However, these algorithms have been considerably updated and expanded with the implementation of new concepts and recent developments in the spectrum analysis and peak deconvolution. The new bAxil calculation and analysis engines take also into account the most recent developments in XRF excitation, detection and electronics technology that has changed the actual ED XRF measurement technique. Updates also allowed the bAxil software to be compatible with Windows PC’s and Mac iOS. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Figure 19., bAxil software display showing different elemental abundances at this particular depth. Y- axis is presented in a log scale. Dark red area is the original spectral data, and peaks represent the number of counts of photons with particular energies Figure 19 displays an XRF spectrum where peaks represent the number of counts of photons with particular energies. Each of these energies are characteristic for a particular element. The bAxil software calculates the ‘area’ under the curves of a wide range elements, allowing the user to see relative intensities and to derive element ratios. This can be seen modelled in yellow. The software also equates for any background noise (green) due to the source and detector, as well as ‘sum’ and ‘escape’ peaks (red and purple). The processing of spectra is defined by a template that is unique to a particular beam condition and defines the elements of interest (Beam 1: 10 kV, Beam 2: 40 kV). Figure 19 displays a single spectra, but bAxil is accompanied by another piece of software, ‘bAxil Batch,’ which can process multiple spectra using a template (Figure 20) and export the data into a convenient CSV file. This is convenient for analysing large numbers of spectra acquired from high-resolution logging of cores. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Figure 20., Template of multi-spectra elemental dataset in bAxil Batch software. 6 GEOTEK SUPPORT AND WARRANTY With more than 260 systems sold world-wide, Geotek have developed a global distributor network allowing for multi-sensor core logging systems to be produced for purchase, lease or service work at all corners of the globe. Furthermore, Geotek have a select team of experienced geologists and engineers who install and give advanced training on such technical equipment, ensuring the user is capable and set for efficient logging techniques. This experienced team are available for remote and on-site support for our global customer base. Geotek design and manufacture the MSCL systems in our warehouse facility in the UK, ensuring the equipment to be sturdy, rugged and flexible for offshore and onshore use, in the lab or in the field. The modular design of the systems allows for customisation and user input when manufacturing, as this may be done on a client to client basis. This also allows for user upgrades, as sensors may be added at a later date dependant on client budget and time- frames. Due to the rugged nature of the equipment, the MSCL systems may last decades, with recommended software and PC upgrades on occasion. Geotek offer a 12 month warranty with all new equipment purchased. After the warranty period Geotek offer multiple levels of cover for support in the form of Gold and Silver service contracts. Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk 6.1 ANNUAL GOLD SERVICE CONTRACT GOLD contracts include parts and labour, with one site call out per year. In the likely event that no specific "call out" is required due to malfunction or failure then the visit will be made to perform a preventative maintenance/calibration/training visit with up to 3 days onsite (depending on specific instruments in cover). GOLD cover also provides annual entitlement to telephone and on line support with "team viewer" online diagnostics where available. Geotek recommends at least a 3 year coverage to allow for an annual check-up and full support throughout the year, rather than multiple service visits (circa EUR 1800/day). Through commitment to a 3+ year contract, customers are offered a 5% discount. 6.2 ANNUAL SILVER SERVICE CONTRACT SILVER contracts include annual entitlement to telephone and on line support with "team viewer" with diagnostics where available. It does not include labour and consumable parts and an annual service and training visit for the MSCL instruments. The silver option does not include any service support visits that may incur. There is, however, a 30% discount on service visits (parts and labour but not including expenses) for silver service contracts. Through commitment to a 3+ year contract, customers are offered a 5% discount. 7 MSCL-XYZ-XRF CUSTOMER REFERENCES Relevant research customers of MSCL-XYZ systems include: • British Geological Survey • Turkish Geological Survey (MTA) • National Oceanography Centre (e.g. Rothwell and Rack, 2006) • International Ocean Drilling Program • Oil and Gas service lab company in Houston • JAMSTEC onboard the D/V Chikyu Geotek MSCL – XYZ – XRF system Geotek Ltd – www.geotek.co.uk Keskkonnaamet Kiirguskaitse büroo Kliima ja kiirgusosakond Teie: 18.08.2022 [email protected] [email protected] Meie: 19.09.2022 nr 9-3/22-262 XRF seadme registreerimine Austatud Richard Lõhkivi Olete edastanud meile KOTKASE infosüsteemis 18.08 teavituse, et XRF seadme kasutamiseks on vajalik esitada kiirgustegevusloa 18/035 muutmise taotlus või uue kiirgustegevuse loa taotlus. Plaanime esitada uue kiirgustegevusloa taotluse, et registreerida olemasolev elektrooniline kiirgusseade (käsi-XRF). Selle kuu alguses hankis EGT lisaks olemasolevale käsi XRF-ile, veel ühe XRF seadme (puursüdamiku skänner). Nimetatud seadme paigaldamine ning tootjapoolne koolitus toimub eeldatavalt oktoobrikuu jooksul ja ilmselt peame registreerima ka selle seadme kiirgustegevusloas. Lisame juurde hangitud seadme tehnilise juhendi, kus tabelis 2 on esitatud kiirgusseadme näitajad. Soovime, et mõlemad XRF seadmed oleksid kantud ühele kiirgustegevusloale. Kuna uus seade pole veel installeeritud ning tootja poolt üle antud ja võttes arvesse uue seadmega töötamiseks vajalikku koolitusele ning nõutud eeskirjade ja juhendite väljatöötamisele kuluvat aega, palume pikendada uue kiirgustegevusloa taotluse esitamise tähtaega kuni 31.12.2022. Lugupidamisega (allkirjastatud digitaalselt) Sirli Sipp Kulli Direktor Fr. R. Kreutzwaldi 5 / 44314 Rakvere / [email protected] / www.egt.ee Registrikood 77000387
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